基于DES方法的平板孤立冷却孔数值模拟研究

本文运用DES(Detached-Eddy Simulation)分离涡方法,对吹风比为0.51和1.04的平板孤立直圆孔和弯圆孔下游的换热特性和漩涡结构进行了数值研究,并简要分析了下游涡量场的结构。模拟结果显示,预测的壁面温度场的趋势与实验值吻合较好;与RANS方法相比,DES方法得到了更加丰富的流场细节和旋涡结构,同时再现了冷却孔下游具有流场的间歇性,对进一步理解和研究冷却孔下游流场内的旋涡结构提供了参考。     

A Monte Carlo study for the shielding of γ backgrounds induced by radionuclides for CDEX

The CDEX (China Dark matter EXperiment) Collaboration will carry out a direct search for WIMPs (Weakly Interacting Massive Particles) using an Ultra-Low Energy Threshold High Purity Germanium (ULE-HPGe) detector at the CJPL (China JinPing deep underground Laboratory). A complex shielding system was designed to reduce backgrounds and a detailed GEANT4 Monte Carlo simulation was performed to study the achievable reduction of γ rays induced by radionuclides and neutron backgrounds by D(γ,n)p reaction. Furthermore, the upper level of allowed radiopurity of shielding materials was estimated under the constraint of the expected goal. Compared with the radiopurity reported by other low-background rare-event experiments, it indicates that the shielding used in the CDEX can be made out of materials with obtainable radiopurity.     

Design and end chamfer simulation of PEFP beam line curved dipole magnets

The design, fabrication and field measurement of 11 DC curved dipole magnets for the PEFP Beam Line have been completed. In this paper, a design method for a complex end chamfer using OPERA-3D is proposed. The conventional method for estimating chamfer shape is extended and applied to a curved dipole magnet by a coordinate transformation. Using the interface with CAD software, the complex end chamfer is modeled and fully determined by 3D simulation to meet the field uniformity requirement. The magnetic field measurement results are in good agreement with the simulation. The design considerations, field simulation results, end chamfer development process and measurement results are presented in detail.     

A study of the active thermal control for the high energy detector on the HXMT

A thermal control system (TCS) based on the resistance heating method is designed for the High Energy Detector (HED) on the Hard X-ray Modulation Telescope (HXMT). The ground-based experiments of the active thermal control for the HED with the TCS are performed in the ambient temperature range from -15 to 20 ℃ by utilizing the pulse width to monitor the interior temperature of a NaI(Tl) crystal. Experimental results show that the NaI(Tl) crystal's interior temperature is from 17.4 to 21.7 ℃ when the temperature of the PMT shell is controlled within (20±3) ℃ with the TCS in the interesting temperature range, and the energy resolution of the HED is maintained at 16.2% @ 122 keV, only a little worse than that of 16.0% obtained at 20 ℃. The average power consumption of the TCS for the HED with a low-emissivity shell is about 4.3 W, which is consistent with the simulation.     

大庆油田和南阳油田采出水的分析

采用高压消解罐法消解处理样品,对大庆油田和南阳油田几个驱块的采出水样品进行了全离子分析.用ICP-AES测定了其中Na、K、Ca、Mg、Al、Ba、Sr、Mn、Si元素的含量.方法回收率在95.00%-106.00%,相对标准偏差小于2.15%.采用离子色谱测定了各驱采出水中Cl<'->、SO<,4><'2->含量,方...     

铁酸镍用于热化学循环反应CO2分解制CO的研究

采用共沉淀法制备了NiFe₂O₄和NiFe₂O₄/ZrO₂催化剂,用TGA考察了其热化学法,CO₂高温分解反应性能。通过对反应前后催化剂的表征发现,反应高温使两种催化剂都发生了明显的烧结,导致在热还原反应中形成的还原态氧化物不能完全被CO₂氧化从而降低了催化剂的反应性能;ZrO₂的加入对于提高催化剂的热稳定性以及循环反应稳定性具有重要的作用。在高温反应炉中考察了NiFe₂O₄/ZrO₂的CO₂分解实验,结果表明,提高热还原温度可以提高CO产量,然而,随着循环次数的增加CO的产量降低得更明显。     

由不同镍盐前体制备高分散Ni/SBA-15催化剂：活化氛围的影响

以硝酸镍和乙酸镍为镍前体,用浸渍法分别在空气和氢气氛围活化制得系列Ni/SBA-15催化剂,通过XRD、H₂-TPD、N₂物理吸附和在线质谱等物理化学手段对催化剂进行了表征,并结合微型高压反应釜萘加氢反应,评价了催化剂的加氢性能。结果表明,氢气氛围活化对硝酸镍为镍前体所制Ni/SBA-15催化剂的镍分散度和活性有显著促进作用,而空气氛围活化对乙酸镍为镍前体所制催化剂有明显促进作用。根据催化剂前体在不同氛围活化时的热分解产物,提出了活化氛围对不同镍前体制得Ni/SBA-15催化剂所产生的作用机理。     

纳米纤维固相萃取-高效液相色谱-荧光检测麻辣烫汤液中喹诺酮类药物

建立了固相萃取-高效液相色谱-荧光检测麻辣烫汤液中5种喹诺酮类抗生素的分析方法。麻辣烫汤液样品经EDTA-Mcllvaine缓冲溶液(pH 4)提取后,以HCX固相萃取小柱净化富集,用水淋洗,2%氨化甲醇洗脱。采用高效液相色谱-荧光检测器(HPLC-FLD),于激发波长280 nm,发射波长450 nm处进行检测,流动相为甲醇-水-磷酸(25∶75∶0.1,V/V,三乙胺调至pH 2.8)。麻辣烫汤液样品中氟罗沙星、诺氟沙星、沙拉沙星、环丙沙星、奥比沙星5种喹诺酮类抗生素加标回收率为72.1%~110.3%;日内相对标准偏差(RSD)为1.6%~4.3%,日间相对标准偏差为2.0%~4.3%;检出限(LOD)为1.2~5.4μg/L;定量限(LOQ)为3.9~18μg/L。本方法能够满足实际麻辣烫汤液样品的分析要求。